聚酯低聚物和聚乙二醇醚对蒙脱土的插层与剥离作用

μ∪1EU。B-0x0↔N8士No.12001 Ae 20AACTA POLYMERICA SINICAFeb. E-2001i° NDWiW0+" io%406￥μ19401r9 1400010 ryANqOAE N lAμA2a2a0e°pAex+0A *0x1i6 0A1u<**"0D1G-A0- ijENSNBWi0° H土N0 10025010%E AENTE"~MNT287a2a0epAeE AO%SI/xEa0Oqb "450￥BHEL-4i00”)4A百“PEGL@。β -0x0>i/2ax" 1eEaNTAEAx。°2Y2AATμAOE土。0f x-EaTBNUEa0CμA1 |AE国40kV/140mAfD)s/Rs/SsμAOxOUx0E>/c”a0UμAO> Aazax"1eEaNT. EU%4BODNo= 1/6*/0. 15/1/6*.AexOE}》》>D010D0/heOEODμAiEAE6DO.0U2a2 MMT 0e BHET >UDμ12>ix"1EaNTODAE IN1AECE1OAvTEOeμAO00. EoμANgMMT 0e BHET NDA$91EOEUi→μA>UDμ12>;iε6C°01μ0EA/2a Sij3O EAAxe ia0D/avD0>2a Aliθ"OH2O -0+00U3εTAei BHET EOμa00ET 30 ~ 40C TANoODD°EAaiaxe3E. 348903E/DDuUuOA 2aAUODES0aμxO1ouA. A00A WAXD 2aI"。+0012i 1r00 MMT 2a%a%aE1Ea”0 , °ug°EC6u0e2avaμAxOOENoAex0 Na+ iK+ ic uAta>~.Ca2+ iMg2+ uE Tμ%μe Eh°alt30a00 laμAμg0D 3 MMT 0e PEG μAE0E012>iD0.MMTT 0e PEG μAEOEU12>iEC0U_ B0U PEC EOEUA0OAAEINMAμANδAe xOE1%>>》ioDork<00>u口TAE 30 ~ 40CμACe ioTA2《IpOBOU>UDUμ/zAeTAXkoAex02a2a1A>o- 0|μ￥iazaEe MMT 2avat61EazaYaD12>i. EuμA2u1TA0OA WAXD 2a"12>i 1T0D MMT4a8A "6f子c 0o40Fa 0U- 0| iaTμ0DμAAOE6D0&&12aV%a84aμAta- .MMT 00-0| 1aTμ0D°pAeiθ0μ￥2a>δEy2E~ YVEC nm 4 MMT 1u y冷BHET 9[ MMT μA2aopAe3B^cEOOEφOUw09TTY>i iaO@ODfDT3EAEAx . °2zABHET ECqOHY%{Ip)/x Ea0e0Olp "4μA.-0|20172-AT. 0aECA0A2a2ay409TOE土_ 0O>u_1P>uAEAx. ,-2Y2AEC PET μAμi -0x0AiEe401Y . /Ea0e MMT 3εTANDA￥ATμADi3E>UAfU1~3PY12>i. [%41 [22> 1-00AiEμA MMT 0e BHET 0∪3γTAMMT q00o>DON090r9r- >fceyU TτOθGiAOμATA>uDμ12,i∩ημA WAXD 6u 20 = 2~ 10μAGuTB.0U1u。/hx=0AE6u i-Nuε00o 6 MMT μuAzavawa&60A'EE“Ae -9TSAUOD MMT μ8"001Q@xe i00-NUEa -a.E1Ea -Eu2aopAe. 0o ”EEia1OAEOEt, ,0D>u.1p >uAEiE"1y Bragg 1 [34349T.d.1n40OuAGuTB 1个”i MMT"EDEOEiE-E?aT"C个0E"EεE%4OEMMT μuAza2a9jpAeECOF+,_ ,B -0x0Vo0O>2/。EOTEOGuTB 2~ 6 -0+0tiE%4 MMT/BHET 00>i/AE INIA。°9I2AATμAEx0@uμA114E610/%U EuECEμTOAi士E≥30% iQ0% j40% iσ%2i 2% . EuACTOE%412AENIA0U. B -0x0>01aOD TU1%AEAx -0Ec9i0e, β -0x0>i10D MMtT"0OlEaxe 100+ -a14301000 20<6°. 2φ>uia0>Uha9UμAO0O@ND%jAUEY.E' i MIMT μ001@aqμAWkGEDi. oaTqxA BHET 0e .4TAI"1yNDWjOU>uDμ°fEEμAx+0ATA MMT 90MMTVE10U32TATA1ii-NDA￥12>i2θ2EYOxt>Tu_。4BHET91 PEG μATu ,hkx+0A.10A0AEEuACri MMT 2a60 MMT 2ay4a£61 Fa2)%aa00 6.CullB 2~ 6 μuAtam-2a0epAex+0A9[>uAi .TOE%26exA BHET 0D MMT μA9-Ai 0 2% 00/￥06%012AAT°1OGE+E士20 0200/￥E03-”6%C作-mhTo0ET9e, βi10δ1￥士必EμNeEu0AμA Na-AE N lASraNoAe x0/%> >>Ya' 6.02341EGEμfMMT 2awa1u ,/2 BHET μAAε -021/4/0Ai e 90mequiv/100g2但300 ~ 400 Ai -0x' jAAEEpf i +A A3C个TAcou 2>A01eETu。%. +iPEG》NS i M。= 600i 4500i2000i 6000f0)/ Max-rAi0.IYH.CN M H CruμAUu_AECOIuA* 199.1116 E的0.20000-22 P . aw0xOE* iENSNSjh&xEUuCTAq >i%b2A 598730219*** F~MA*IμE1241EUOx 1016μE2906￥μ1401τ9 [00 "VANqOAE IN1AμA2a2a0e opAex-OA125E0EU12>" iACNuNOEa . aTdEsEHeE i→E-0t0Ta0!1u. /&Ey2aj<2a9iμ￥za PEG -0xGO5Y? EaE> PEG 0220D°o_ 9μc∈EμAN60_ xOEHx >a16 BHET ACNup1%OA MMT leEA+ T0. 0>3010μ￥0>Ci_ ,0 °6μA-a d=1. 8nm.0aEGOEOU PEG 0+ 02 00μ￥2aDiEh2”a0u0020()MMT 2aV4aμAva10.Fig. 1 WAXD curves of blends from MNT and BHET at30CE"1E@C" 62@MMT contents are respectively 02802202 40E5E>J22wt%Ec100N BHET 40Eqμ%, BOUEaEOEUTATEOOET 30~ 40CE4O DDEDOEU>uDμ12i . μAμ/k2uTYμA WAXDCuTBEc [%4 2. 1%40DμA5 ioGuTB 1~ 5 -00tiE%420(")MMT/BHET 00Ai E个@ 30% i20% id0%i5% 2[2% . EuACTOE%600 MMT 9-AjTE 5% 001AE土568~001E0Fig. 2 WAXD curves of melted blends from MMT and BHETAayμANOEa -a>∪+%T0∈SE+1A=0Dxa1>AiμA BHET 2a"1E0C”5&@MMT contents are respectively 30220E#0LSE2wt%Ee MMT 2a1afZ>> μi EtμANOEa-a"6 6(6E6 EμA+OUEOEU>GDμ12rjμACeε0TAE→MMT A01u。%经°6AεμA BHETEEOIoE1 MNT 2avaμAV6991A!°61≌v6E6 .0ajEAUEC+>个o ,%uA BHET 6￥>心ET o0Dx00Eμc x0μAN60- x0i MMT 2aN4aN6Aex0-cEuA300Ac9Tx-0AE%6E6AE910= ia2aμA%2μgWa9Iηρ0A./400@ BHET μAEEOEC~E1 MMT -CEuza°pAE4EYTtμ< MMT 9-Ai3-1y 10% f88"0012TeuANOEa -a%TOD20 ()EcT0E%4E+iA=' E仕MMT 2>A0 ieEuA1>10D Ylho0o>2%/NDWi.5 MMT 90 PEG uATu ,lx+OAEμNe)a 10>1 0A+20U PEG μA -0x0Ai 600 ~1%43 EC MMT/PEG E0E012>iTTμA WAXD Cu6000 μA -9iSAU&60E012>>i E士%aNOa0A 6h&EuμAWaTB . CuTB 1ie9i3 -0t土iE% MNT9-Ai -0t01β 2% ic中国煤化工5%2i 20%2Taμ400 PEG μA00Ai叫-0Ey£@ EuOAPEG -0x0Ai个@ 2000. EμNe0x∈μ0∪2θ= 1.5~ 100目YHCNMHGVafPEG 2>3610NUEa -asθo”E20U 'E -9TSAUμANUEa-aO>AUEC MNT μ~ 001aNOEa -a.0140DiE00;°36EMMT 9-Ai0U.2%9f 5% E+E2>T6 BHET9f MMT万月数据1260NS+2001 AeREFERENCESKojime YEtUsuki AEKawasumi MEOkada AfKurauchi TEKannigato 0. Jouranl of Polymer ScienceEPart AfPolymer Chemtisty£t99323129755 ~ 17582 Usuki AEKoiwai AEKojime YEKawasumi MEOkada AEKurauchi TEKanigato 0. Joumnal of Applied Polymer Science£+995855919~ 1233 Zhang Guoy& 0A10